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Cyclohexanes

Dear Reader,

Here are two more cyclohexanes for you to look at to help you deal with them.

22
XYZ file : trans 1,2-methylcyclohexanol with the groups in the equatorial sites
C(1) 1.6842 0.0890 1.0523
C(2) 0.4282 0.6216 1.7550
C(3) -0.8358 -0.0330 1.1796
C(4) -0.9389 0.1799 -0.3419
C(5) 0.3266 -0.3398 -1.0311
C(6) 1.5871 0.3103 -0.4632
O(7) 0.2664 -0.0735 -2.4130
C(8) -2.2083 -0.4932 -0.8911
H(9) 2.5920 0.5983 1.4553
H(10) 1.7967 -1.0010 1.2638
H(11) 0.4940 0.4246 2.8519
H(12) 0.3678 1.7282 1.6233
H(13) -1.7363 0.3895 1.6859
H(14) -0.8171 -1.1263 1.4012
H(15) -1.0182 1.2792 -0.5358
H(16) 0.3928 -1.4471 -0.9196
H(17) 2.4909 -0.1099 -0.9656
H(18) 1.5717 1.4054 -0.6768
H(19) 1.0395 -0.4491 -2.8414
H(20) -2.3404 -0.2956 -1.9788
H(21) -3.1195 -0.1116 -0.3766
H(22) -2.1736 -1.5969 -0.7469

 

While here is the same molecule in the conformation where the groups are both axial.

 

22
XYZ file : trans 1,2-methylcyclohexanol with groups in the axial sites
C(1) 0.6378 -1.0682 1.0575
C(2) 1.4238 0.2358 1.0213
C(3) 0.5241 1.3571 0.5184
C(4) 0.0311 1.0225 -0.8832
C(5) -0.7550 -0.2815 -0.8469
C(6) 0.1447 -1.4027 -0.3441
C(7) -1.9468 -0.1293 0.0891
O(8) 1.1294 0.8817 -1.7431
H(9) 1.2958 -1.8875 1.4243
H(10) -0.2336 -0.9574 1.7409
H(11) 1.7834 0.4804 2.0458
H(12) 2.2956 0.1249 0.3382
H(13) 1.0991 2.3097 0.4915
H(14) -0.3474 1.4683 1.2017
H(15) -0.6261 1.8420 -1.2510
H(16) -1.1158 -0.5260 -1.8710
H(17) -0.4302 -2.3554 -0.3172
H(18) 1.0162 -1.5140 -1.0275
H(19) -2.5219 -1.0818 0.1162
H(20) -2.6042 0.6901 -0.2785
H(21) -1.5853 0.1150 1.1130
H(22) 0.7852 0.6761 -2.5956
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One Response

  1. Which type of cyclohexane molecule would be produced when benzene converted to cyclohexane on platinum catalyst.

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