I imagine that you have seen the suggestions by fusion experts that nuclear fusion will give us a cheap, safe, clean and green source of energy which will provide power for the world’s needs. I am currently thinking about how green is fusion, right now I have contacted a fusion expert who I know and I am awaiting his views on the matter.
While we are waiting I think it is important to ask the question of what was is the typical cause of a nuclear accident. Is it a issue with management, an “act of god“ or was it a technical failure ?
In the case of the Windscale fire I have seen suggestions that it was human error, poor design of the reactor or mismanagement of the project. I know that before the 1999 Tokaimura that a criticality accident at the JCO site was considered to be a was considered to “be an unrealistic scenario” according to the UN report on the accident.
I have to ask the question, did a failure in a regulatory body (either the external state regulator or the companies own internal regulation) cause the first step to be taken which lead to the accident in 1999.
One model of how accidents occur is the Swiss cheese model, the idea is that a weakness in a system is like a void in a lump of cheese. Due to some event a void can appear in the organisation, this void can grow in size, shrink, vanish or move around. As long as some solid cheese exists which prevents a path existing from one side of the block of cheese to the other then everyone is “safe”.
But when a series of holes align themselves to create a path through the cheese block then an accident occurs and then the airplane crashes, the core melts or some other horrible outcome occurs. In some ways the most important step is for the plant owner or the management is to recognise that a given type of accident is possible.
This first step of admitting that a given accident type is at least a theoretical possibility enables the company to start to take steps to prevent it occurring. For example the understanding that someone could get a body part caught in the moving parts of a machine lead to the idea of the 19th century UK law which requires where possible all moving parts of machines to be fenced off or guarded.
While it is impossible to fence off some moving parts such as the chain of a chain saw or all the parts of a handheld electric drill, this law does improve safety by greatly reducing the number of moving parts which can cause injury to factory workers. In the same way if a fusion reactor is going to be built we need a good understanding of the possible threats which it poses.
One is the beryllium used in the heat transfer fluid in some designs, I was reading recently about fusion reactor safety and I saw that a mixed lithium / beryllium fluoride has been proposed as a tritium breeding layer and as a heat transfer layer. I can tell you that beryllium is a very nasty element, in some ways it is worse than some of the radioactive elements. As a result special care will be needed if beryllium or its compounds are used in fusion reactors.
I have looked at the crystal structure of Li2BeF4 (J.H. Burns and E.K. Gordon, Acta Crystallographica, 1967, 1, 1948-1923), this is an interesting looking 3D network. But before we get stuck into it we should look at some organic salts of “H2BeF4″. L.A.Gerrard and M.T.Weller (Acta Crystallogr.,Sect.C:Cryst.Struct.Commun., 2002, 58, m407) report a nice and simple tetrahedral BeF4 unit which has protonated DABCO as the counterion. Those of you who know VSEPR should have predicted that one OK. Here is a picture of the anion in the solid.
The tetrahedral BeF4 dianion
If we have less fluorides per beryllium centre (to make the Be:F ratio 2:7) then we need to use one of the fluorides as a bridging ligand to give us four electron pairs (eight electrons) around all the metal centres. Then we get the following dinuclear complex. See S. Aleonard and M.-F. Gorius (C.R.Seances Acad.Sci.,Ser.II, 1989, 309, 683)
The BeF7 trianion
If we go a little further and have a Be:F ratio of 1:3 then we will end up with a dinuclear complex which has two bridging flourides. This is shown below. (B. Neumuller and K. Dehnicke, Z.Anorg.Allg.Chem., 2005,631, 2535)
The Be2F6 dianion, note the SiF6 dianion in the right of the picture
And now for something completely different (sorry no monty python for you today) if we mix lithium and beryllium fluorides with an salt of an amine fluoride to give us Li2Be4F14 in the unit cell (L.A. Gerrard and M.T. Weller, Chem.Commun., 2003, 716 ). This network will have a charge of -4 and it will form long strips of metal atoms which are in a 1D coordination polymer. Here is the picture for you of the metal atoms and flouride anions in the unit cell.
The metal and flourine atoms in one unit cell
How here are two strips of metal atoms side by side.
Two strips side by side, note that there are no interconnections between the strips
Now here is four strips viewed from a different angle.
Four strips viewed from a different angle, note that they do not touch each other
Now if we look at Li2BeF4 we will see it is a complex solid, I have looked and all the metal atoms have tetrahedral environments, here are a series of views of the unit cell to show you what the solid looks like. This is going to be hard, it is a 3D coordination polymer. These 3D coordination polymers can turn out to be what I call “atomic fog” but this one is not too bad, I have seen much worse in my time.
Side view of Li2BeF4 cell showing the bonds going in one dirrection
Now after turning by 10 degrees
Now the end view.
One last thing in case any of my readers are thinking of doing beryllium chemistry, my short answer is “do not do it !“. Beryllium is the most toxic non radioactive element, some forms of it are almost as bad gram for gram as Pu-239. In some ways I would like John Hunt (the voice of the UK’s AIDS advert) to dispense advice to you about beryllium chemistry using the voice of doom, but you just have me right now.
I would suggest that if any chemistry students do not want to turn back and do something else then I suggest they talk to your local friendly radiochemist and learn how to work with gram amounts of plutonium. Then do the beryllium chemistry in the same way using negative pressure boxes and all the other safety precautions which you would use for large scale Pu work.
Filed under: beryllium, coordination polymers, crystallography, crystals, Fukushima, fusion, nuclear chemistry, nuclear technology, Uncategorized | 2 Comments »